Effect of Pressure on Iodine Complexes. I. Absorption Spectra of the Visible Iodine Bands with Diethyl Ether, Diethyl Sulfide, and Diethyl Selenide in Heptane
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چکیده
منابع مشابه
Hyperconjugation in diethyl ether cation versus diethyl sulfide cation.
Ionization of a molecule can greatly alter its electronic structure as well as its geometric structure. In this collaborative experimental and theoretical study, we examined variance in hyperconjugation upon ionization of diethyl ether (DEE) and diethyl sulfide (DES). We obtained the experimental gas phase vibrational spectra of DEE, DES, DEE(+), DES(+), DEE(+)-Ar, and DES(+)-Ar in the wavenumb...
متن کاملA mechanistic and experimental study on the diethyl ether oxidation
This work presents the results of the theoretical investigations on autoxidation process of diethyl ether (DEE), a chemical largely used as solvent in laboratories and considered to be responsible for various accidents. Based on Density Functional Theory (DFT) calculations, the aims of this study were the identification of all the most probable reaction paths involved in DEE oxidation (at ambie...
متن کاملThe low-temperature structure of diethyl ether magnesium oxybromide
The crystal structure of the title compound, hexa-μ(2)-bromido-μ(4)-oxido-tetra-kis-[(diethyl ether)magnesium], [Mg(4)Br(6)O(C(4)H(10)O)(4)], determined from data measured at 173 K, differs from the previously known structure of diethyl ether magnesium oxybromide, which was determined from room-temperature data [Stucky & Rundle (1964 ▶). J. Am. Chem. Soc. 86, 4821-4825]. The title compound crys...
متن کاملMeasurements of Flat-Flame Velocities of Diethyl Ether in Air.
This study presents new adiabatic laminar burning velocities of diethyl ether in air, measured on a flat-flame burner using the heat flux method. The experimental pressure was 1 atm and temperatures of the fresh gas mixture ranged from 298 to 398 K. Flame velocities were recorded at equivalence ratios from 0.55 to 1.60, for which stabilization of the flame was possible. The maximum laminar burn...
متن کاملNeurophysiological Studies on Nitrous Oxide and Diethyl Ether Anaesthesia.
The spontaneous electrical activities and alterations of the activation threshold of the neo-, palaeoand archicortical systems were investigated during nitrous oxide and ether anaesthesia. In the neocortical system the threshold for hypothalamic stimulation, induced spindle bursts, recruiting response and thalamic arousal reaction were also examined. The results obtained were as follows: (a) Ni...
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ژورنال
عنوان ژورنال: Bulletin of the Chemical Society of Japan
سال: 1979
ISSN: 0009-2673,1348-0634
DOI: 10.1246/bcsj.52.281